Step 2 - Distill

Step 2 - Distill 

Introduction

Distillation is a process of separating alcohol from water using heat as a catalyst. This was accomplished in the original RSO recipe by using a Crock Pot, Rice Cooker, or other electric cooking appliances. These devices are considered open boilers as they vent the evaporated solvent into open air. Larger extractions can use a small countertop Moonshine Still on a hotplate or a standalone water distiller with heating element and built-in condenser. 

WARNING: DO NOT DISTILL ANYWHERE NEAR OPEN FLAME. Always distill in well ventilated spaces using electric heat. The fumes from the solvent are very flammable.

A Simple Hack

This process uses Distilled Water to assist boiling out the alcohol. In the past, water in the wash has been avoided. Rick Simpson actually added 10 drops of water during the the final purge. The presence of water plays a role in cleaning and protecting the oil. Distilled Water provides two benefits. The ion-free water pulls water-soluble compounds out of the oil and provides heat protection through vaporization effectively holding down the temperature. This way, the oil isn't overheated during the bulk alcohol reduction. The end result are oils purged of most polar and semi-polar compounds leaving the oils in a purer state that is easier to winterize. 

Procedure Summary

Basic concept - Pour the clean wash into a boiler, add some water, and boil away the alcohol. Once it reaches 87c/190f, turn off the heat, let it cool down for 10 minutes. You should be at peak floating oil. Add ice water to the boiler to bring it down to 10c/50f. Use a fork to secure the floating oils to the boiler walls. Pour out the waste water through a 300 MESH stainless steel fabric to retain loose oils and sediments. Dissolve the oils with Ethanol and you're ready for the next step. That's the concept. Here are the details for each type of distiller. 

Three different classes of devices are available for distilling down the oil.

1. The first is an open boiler run as a single pan on heat or a double boiler setup. 

2. The second device is a moonshine still that is the only device properly engineered for alcohol recovery. 

3. The third device typically used is a consumer water distiller. Water distillers are popular for trying to recover alcohol, but are not setup correctly so up to 1/3 of the alcohol vapor can be lost into open air.  

The double boiler approach allows the distilling temperature to be maintained at a constant level. It's the added water that limits the heat.  The above images show the boiler setups that doesn’t recover the alcohol. If you have large batches or wish to recover the alcohol, then a small Moonshine Still is in order. Again, its all about controlling the temperature. Crock Pots, Rice Cookers and Water Distillers are harder to control the input heat; you get whatever the device is designed to deliver.  Here's a simple procedure -

• Pour in 12cm/0.5in of distilled water into the boiler.

• Pour in the alcohol wash.

• Once the top boiler reaches 87c/190f, distilling is done, turn off the heat.

continue to the Common Ending below..

Using a moonshine still is very straight forward. As shown above, the still has two hoses on the right for circulating water through the condenser, and a tube on the left for collecting the alcohol into a capture jar. Out of sight in the bucket is a little 3 watt aquarium pump that drives water into the condenser. Here's the procedure for using this setup - 

• Add 500ml/2 cups of distilled water to the boiler.

• Add the wash. 

• Set the lid and condenser in place and latch it down.

• Power up the water pump and turn the hotplate to full power.

• Watch the temperature gauge. Once it reaches 80c/178f, turn the power down to 1/3 power. Once producting, the alcohol will start dripping into the collection jar. The output will range from slow dripping to a continuous stream depending on the amount of power. Proper power setting will be in the middle where the stream cycles between dripping and flowing.

• Once the temperature rises above 85c/185f, swap capture jars. 

• Once the temperature reaches 87c/190f, turn off the power. Let it cool down for 10 minutes.

• After 10 minute, take the condenser off and set the boiler in a sink or bathtub of ice cold water.

Continue to the Common Ending below

The better water distillers have a temperature control panel on the front allowing you to set the ending temperature. Simple On/Off devices offer no ending temperature control, so these units may go dry by boiling off all the water before shutting down. This will cook the oils, not a good thing..

Best way to use a water distiller is to set the Stop Temperature to 85c/185f. Let it shut down. Wait 10 minutes, then unplug and remove the condenser. 

• Add 2 cup of distilled water to the boiler.

• Pour the wash into the boiler.

• Install the condenser and plug it in to the base.

• Set up the capture jar.

• Power up and set the Stop Temperature to 85c/185f.

• Once stopped, let set for 15 minutes to cool down. 

Continue on..

Common Ending

All three devices will have oil in various states. You could have floating oil, oil adhering to the boiler walls, or black sediments settling to the bottom. Here's how to collect the oil. NOTE: An accurate digital thermometer is required for this to work.

• Allow the boiler to cool for 10 minutes after turning off the heat.

• After 10 minutes, bring the temperature down to 10c/50f by adding ice water. If possible, place the open boiler or moonshine still in a sink or bathtub of cold water. 

• Use a fork to press any floating oil against the cold boiler walls. 

• CAREFULLY pour the waste water through a 300 MESH screen to retain any oils and sediments. 

• Rinse the boiler with cold tap water, the oil will remain stuck to the bare metal. Drain the water through the mesh filter to catch any final sediments.

• Allow the boiler to dry.

• Place the mesh filter in a small pint jar. Add 1-2oz warm ethanol and shake hard to dissolve all the oils. 

• Pour this alcohol into this boiler and dissolve these oils. Quantity should be approximately 10 parts alcohol to 1 par oil. Use only high proof alcohol here.

• Warm up the boiler in the sink using hot water. For water distillers, turn on the power for a few seconds. Power off if simmering. Steam indicates its too warm. 

• Use a silicone spatula to dissolve the oil in the warm alcohol.

• Pour the oil laden alcohol in a small metal bowl for the upcoming Winterize step.

• Pour an ounce more Ethanol in the boiler to clean it up. Pour this alcohol in a small jar for the freezer.

You now have a bowl with the dissolve oils and a small jar with about an ounce of alcohol. 

Troubleshooting

1) No floating oil at the end.  

In most cases, once distilling stops at 87c/190f, there should be peak oil floating on the water surface and adhering to the boiler walls. If the heat is allowed to reach 93c/200f, then the floating oil may ball up and sink to the bottom as sediments. It's all good. This is influenced by the denaturing of plant proteins. The sediments can be thought of as miscelles with a polar surface and non-polar insides. This is why the sediment will not attach to the body of oil. It's skin is made up of polar compounds keeping the oils apart. Use cold temperatures and you can save both. Use a 300 MESH screen folded into a cup. Once the waste water is chilled down to 10c/50f, pour the waste water through this mesh filter to capture loose oil and sediments. This mesh filter is cleaned up in the above 'Common Ending' paragraph.

Tips and Tools

Tip: Using a Moonshine Still:

When using a moonshine still to recapture the alcohol, the temperature will rise to alcohol's boiling point and stay there for a long time. The length of time is determined by the ratio of alcohol to water. Once the ratio starts leaning towards water, the temperature again starts to rise. Once you see the temperature rise to 87c/190f, turn off the power and save the capture jar. This jar will hold the maximum concentration of alcohol, either 91% Isopropyl or 95% Ethanol. 

Tip: Using 99% Isopropyl Alcohol for Extractions:

When boiling off 99% Isopropyl, some water will be stolen from the pool of distilled water to form 91% Isopropyl. This could lead to running the boiler dry, exposing the oils to uncontrolled spiking temperatures.  Ask me how I know.. :)  So the recommendation is to double the amount of added distilled water. This adds a safety margin to avoid scortching the oil.

Tip: Using a Water Distiller:

When using a water distiller to recapture the alcohol, its critical to use one with a programmable ending temperature.  Simple units with an on/off button do not give you control to shutoff, thus may boil off all the water and cook the oil.  

Power up the unit and set the ending temperature to 85c/185f. The unit will run up to alcohol's boiling point and stay there for a long time. The length of time is determined by the ratio of alcohol to water. Once the ration starts leaning towards water, the temperature starts to rise and the unit will shut down. At this point, let it cool for 10 minutes, then unplug the condenser and remove it completely. Any remaining alcohol will evaporate off. Then you can pour in ice water to cool the solution to 10c/50f. Go read the 'Common Ending' above.

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